Download Compounds of Arsenic, Antimony, and Bismuth: Covering the by Michael Dub (auth.), Michael Dub (eds.) PDF

By Michael Dub (auth.), Michael Dub (eds.)

The goal of this compilation has been to supply a finished, non-criti­ cal resource of data pertaining to organometallic compounds. The scope is proscribed to the compounds containing at the very least one carbon-metal bond. The in­ formation contains tools of coaching, homes, chemical reactions, and functions. the 1st variation comprised the literature from 1937 to 1958. the second one variation is totally revised and prolonged via 1964. The literature sooner than 1937 used to be completely coated through E. Krause and A. von Grosse in I~ie Chemie der meta11-organischen Verbindungen, " Verlag von Gebrueder Borntraeger, Berlin, 1937. Our paintings comprises 3 volumes. quantity I includes derivatives of the transition metals of teams III via VIII of the Periodic desk. quantity II comprises derivatives of germanium, tin, and lead. quantity III comprises derivatives of arsenic, antimony, and bismuth. The compilation relies on searches via Chemical Abstracts. The col­ lection of references for 1964 was once accomplished ahead of the topic Indexes to Volumes 60 and sixty one of the Abstracts have been to be had; therefore a few omissions within the assurance of that yr are attainable. we've got tried to make the insurance of the literature whole so that the compilation could have most sensible software to the chemist, chemical engineer, patent legal professional, and editor. within the curiosity of brevity, convinced numerical info are passed over, yet references to the unique literature are given. Yield info are rounded to 2 major figures. anywhere attainable, tables were used. The entries within the Bibliography part contain references to Chemical Abstracts.

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Extra resources for Compounds of Arsenic, Antimony, and Bismuth: Covering the Literature from 1937 to 1964

Sample text

SF4 - Phs AsF2 (1577). I - the polyiodide; the rxn. is useful as a spot test for PhsAs (1482). [4-MeCeH4s12o - PhsAsO and (4-MeCeH4S-)2 (1718). 2,4,4-Trimethyl-l-pyrroline-l-oxide - PhsAsO and 2,4,4-trimethylpyrroline (1703) • N202 (attempted) (1864). Raney Ni in xylene under reflux - Ph2 (1889). S02C12, followed by H2S - PhsAsS (1905). MeO~C=CC02Me - MeO~C(=0)C(=AsPhs)C02Me O:! MeO~C(0-)=C(As+Phs)C02Me (1932). PhNs (1:1), followed by Mel and AgBF4 - [Ag(AsPhS)4]BF4 (2132). AgBF4 - [Ag(AsPhS)4]BF4 (2132).

KGl + HCl; mol. condo data (1721). [CU(ArS)2][CuBr2], colorless crystals, prepd. in a similar manner as the preceding complex from CU2Br2; mol. condo data (1721). [Cu(Ars)2][CuI2], colorless crystals, prepd. in a similar manner as the preceding complex from CU2I2; mol. condo data (1721). , prepd. from (Ars) in EtOH and aq. CUS04 contg. HCl04, mol. condo data (1721). ) [Pd(Ars)C12], yellowisr. brown crystals, prepd. from (Ars) and K2[PdC14]; mol. condo data (1721). [Pd(Ars)Br2], orange crystals, prepd.

Na in NBs at -75°, followed by (-CH2Cl)2 - (-CH2AsPh2)2 (1751). [Ph2IJBF4 - [Ph4As]BF4 (779, 905). NH2Cl - [Phs AsNH2]cl (1359). SOs in (-CH2Cl)2 - [PhsAsSOsJ (1456). B2Re in a sealed tube - [PhsAsBRsJ (1456). SF4 - Phs AsF2 (1577). I - the polyiodide; the rxn. is useful as a spot test for PhsAs (1482). [4-MeCeH4s12o - PhsAsO and (4-MeCeH4S-)2 (1718). 2,4,4-Trimethyl-l-pyrroline-l-oxide - PhsAsO and 2,4,4-trimethylpyrroline (1703) • N202 (attempted) (1864). Raney Ni in xylene under reflux - Ph2 (1889).

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